thermal runaway, cell venting, cascading thermal runaway, delayed cascading, deep seated fire
Category
Battery
Thermal runaway in a lithium-ion cell is an internal chemical reaction that releases heat. It can keep going without oxygen and without any visible flame, so it is not the same thing as an ordinary fire. A cell first becomes unstable and gives off gas. Its voltage then drops to zero as an internal short dumps all of its stored energy, and the temperature can briefly reach 300 to 600 °C. Any electrical, thermal or mechanical abuse can start it, and so can an internal defect. At the McMicken BESS, lithium plating and dendrite growth inside a cell caused the internal short. When cells are tightly packed with no thermal barrier, heat passes from cell to cell and module to module. Leftover heat can restart cascading minutes after the fire appears to be out. Runaway without flame gives off toxic and flammable gases such as H2, CO, HCl, HCN and HF. These gases can collect in a closed enclosure and explode. Clean-agent suppression such as Novec 1230 does not stop cascading. Heat must be removed, for example by cooling with water, or the fuel must be dispersed. Design controls include thermal barriers between cells, liquid cooling, air gaps, smaller compartmentalized battery groups, and ventilation to open air. Crews need training and emergency response procedures that cover cascading runaway, flammable gases, and safe entry into a system after a failure.
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sentence 5: support check: partial - The passages support flame-free runaway, the toxic and flammable gases listed, and explosion at McMicken, but the gases H2, CO, HCl, HCN and HF are listed as emissions of the secondary burn rather than of flameless runaway.
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Thermal or physical barriers between cells and modules, such as aluminum plates, heat-resistant plastics, intumescent or phase change materials, slow or stop cascading from cell to cell. Missing barriers contributed to cascading at McMicken.
Cooling plates in contact with a water or glycol loop pull heat away from neighboring cells. The report rates this better than air cooling or plain plates that have no heat sink.